|Table of Contents|

Capacitance Performance of Carbon Atom Wires Electrode for Supercapacitors(PDF)

《南京师大学报（自然科学版）》[ISSN:1001-4616/CN:32-1239/N]

Issue:
2010年03期
Page:
61-65
Research Field:
化学
Publishing date:

Info

Title:
Capacitance Performance of Carbon Atom Wires Electrode for Supercapacitors
Author(s):
Chen Qiaoling1; Xue Kuanhong2
1.College of Chemistry and Chemical Engineering,Nanjing University of Technology,Nanjing 210009,China 2. School of Ch em istry and Environm ental S cience, Nan jing N orm alUn ivers ity, N an jing 210097, China
Keywords:
carbon atom w ires;  supercapac itors;  capacitance perform ances
PACS:
TM53
DOI:
-
Abstract:
A novel carbon m a terial nam ed carbon atom w ires( CAW ) is used fo r e lec trode m ater ia l in supercapacitors. The CAW is fabricated by the py ro lysis o f starch cata lyzed by Fe and treated by concentrated nitr ic ac id to be surface functionalized. The capac itance per fo rm ance of the trea ted- CAW e lectrode is investigated by use o f the cyc lic vo ltamm etry, ga lv anosta tic charge /d ischarge and AC im pedance me thods. The resu lts show ed that the specific capac itance o f 256 F /g o f the e lectrode is ach ieved w ith the d ischarg e current density of 0.2 A / g in the solution o f 5 mo l/L H2 SO 4. In add ition, the treated-CAW e lectrode is found to have low equivalen t ser ies resistance ( ESR) and good cyc ling stab ility.

References:

[ 1] M iller J R, Burke A F. E lec tro chem ica l capac itors cha llenges and oppo rtun ities for rea-l wo rld applications[ J]. In terface, 2008, 17( 1): 53-57.
[ 2] N ao iK, S imon P. New m ater ia ls and new configura tions for adv anced electrochem ial capac ito rs[ J]. Interface, 2008, 17( 1): 34-37.
[ 3] Chen Q L, XueK H, ShenW, et a.l Fabrication and e lectrochem ica l properties o f carbon nanotube a rray electrode for supercapacitors[ J] . E lectrochim Acta, 2004, 49( 24): 4 157-4 161.
[ 4] K im Y J, Jang IY, EndoM. Carbon m ater ia ls fo r supercapacitors[ J] . C arbon, 2009, 47( 5): 1 412-1 413.
[ 5] Dan ie l B, Th ierry B, JeffreyW. M anganese ox ides: battery m ater ia lsm ake the leap to e lectrochem ica l capacito rs[ J]. Interface, 2008, 17( 1): 49-52.
[ 6] 陈洁, 黄可龙, 刘素琴. 球形纳米Fe3O4 的制备及超级电容性能研究[ J]. 无机化学学报, 2008, 24( 4): 621-626.
[ 7] W ang Q, L i J L, Gao F, et a.l A ctivated carbon coated w ith po lyaniline as an electrodem a terial in supe rcapac itors[ J]. Carbon, 2009, 47( 1): 353-354.
[ 8] W ang Y G, L iH Q, Xia Y Y. O rdered wh isker like polyan iline grown on the surface o fm esoporous carbon and its e lectrochem ica l capac itance performance[ J] . AdvM a t, 2006, 18( 19): 2 619-2 623.
[ 9] Burke A. R&D considerations fo r the perform ance and app lication of electrochem ical capac itors[ J] . E lectrochim Ac ta, 2007, 53( 3): 1 083-1 091.
[ 10] Raymundo-P inero E, Le roux F, Begu in F. A h igh-performance carbon for supercapacitors obta ined by carbon ization of a seaweed b iopolym e r[ J]. AdvM at, 2006, 18( 14): 1 877-1 882.
[ 11] O livares-M ar?M, Fern?ndez J A, L?zaroM J, e t. a .l Cherry stones as precursor o f activated carbons for supe rcapac itors[ J]. M ater Chem Phys, 2009, 114( 1): 323-327.
[ 12] Xue K H, Tao F F, ShenW, e t a.l L inear carbon a llotrope- carbon a tom w ires prepared by pyro lysis o f starch [ J]. Chem Phys Lett, 2004, 385( 5 /6) : 477-480.
[ 13] 薛宽宏, 何春健, 陈巧玲, 等. 碳原子线以及固态碳源热解制备碳纳米管和碳原子线的方法: 中国, ZL02 1 2451717 [ P]. 2007-01-10.
[ 14] L in C, R itter J A, Popov B N. Deve lopm ent o f carbon-m e tal ox ide supercapacitors from so-l gel der ived carbon- ruthen ium xeroge ls[ J]. J E lec trochem Soc, 1999, 146( 9) : 3 155-3 160.
[ 15] Kotz R, C arlenM. Princ iples and app lications of e lec tro chem ica l capac itors[ J] . E lectroch im Acta, 2000, 45( 15 /16): 2 483-2 498.

Memo

Memo:
-
Last Update: 2013-04-08