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《南京师大学报（自然科学版）》[ISSN:1001-4616/CN:32-1239/N]

Issue:

2015年03期

Page:

25-

Research Field:

化学

Publishing date:

Info

Title:

SynthesisofPolyoxometalates-BasedCompoundwithSolomonStarStructureanditsCatalysisofAspirinSynthesis

Author(s):

ZhangQiannan; WangXiaoqiu; LanTianchi; FengGuanying; LiuLuying; MengXiangying; ShaJingquan

TheProvincialKeyLaboratoryofBiologicalMedicineFormulation，JiamusiUniversity，Jiamusi154007，China

Keywords:

Wells-Dawsonpolyoxometalate; doublewavelengthUV; esterificationreaction; catalyticactivity

PACS:

O611.4

DOI:

-

Abstract:

Anewpolyoxometaltes-basedcompound，［Cu₉（2-pytz）₆（H₂O）₆（OH）₆（P2W₁₈O₆₂）］·3H₂O，wassynthesizedbythehydrothermalmethodandcharacterizedbyIR，elementalanalyses，PXRDandsingle-crystalX-raystructuralanalyses，inwhichWells-DawsonpolyoxometalateactsastemplateandCu-pytzcoordinationcomplexassecondarystructuralbuildingunits（SBUs）.Meanwhile，bydoublewavelengthUVmethod，westudiedthecatalyticsynthesisofAspirinbyemployingthenewcompoundasthesolid-acidcatalystsindetail，andtheresultsshowthatthenewcompoundhassuperiorcatalyticactivityonsynthesisofAspirin.

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Memo

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Common functions

Last Update: 2015-09-30