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Photocatalyzed Homo-Coupling of α-Amino Acid Derivatives Promoted by Sulfur Hexafluoride(PDF)

《南京师大学报（自然科学版）》[ISSN:1001-4616/CN:32-1239/N]

Issue:
2025年01期
Page:
13-17
Research Field:
化学
Publishing date:

Info

Title:
Photocatalyzed Homo-Coupling of α-Amino Acid Derivatives Promoted by Sulfur Hexafluoride
Author(s):
Zhao Yue1; Zhu Shan1; Ma Fengxiang1; Zhu feng1; Cao Jun1; Hang Chen1; Chen Yifeng2; Zhang Lijiao2; Xie Langui2
(1.State Grid Anhui Electric Power Research Institute,Hefei 230601,China)
(2.School of Chemistry and Materials Science,Nanjing Normal University,Nanjing 210023,China)
Keywords:
sulfur hexafluoride(SF6); photocatalysis; C—C bond coupling
PACS:
O621.3
DOI:
10.3969/j.issn.1001-4616.2025.01.003
Abstract:
Sulfur hexafluoride(SF6)is widely used in the electrical industry as insulating gas,and its global warming potential is 23 500 times of carbon dioxide(CO2). However,SF6 is extremely inert,and its degradation and utilization are highly challenging. In this study,we have found that the SF6 promoted C—C bond coupling with α-amino acid derivatives as the substrates could be achieved under the conditions of photocatalysis at ambient temperature and atmospheric pressure. The studies show that solvents,reaction time and concentrations of substrates are important factors for the efficiency of the reactions. These findings showcase a new strategy for the efficiently photo-catalyzed degradation and utilization of SF6 gas.

References:

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Last Update: 2025-02-15