[1]张 睿.两种不对称四硫富瓦烯衍生物的合成、结构及电化学行为研究[J].南京师大学报(自然科学版),2013,36(02):61-66.
 Zhang Rui.Synthesis,Structures and Electrochemical Properties of Two New Asymmetric Tetrathiafulvalene Derivatives[J].Journal of Nanjing Normal University(Natural Science Edition),2013,36(02):61-66.
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两种不对称四硫富瓦烯衍生物的合成、结构及电化学行为研究()
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《南京师大学报(自然科学版)》[ISSN:1001-4616/CN:32-1239/N]

卷:
第36卷
期数:
2013年02期
页码:
61-66
栏目:
化学
出版日期:
2013-06-30

文章信息/Info

Title:
Synthesis,Structures and Electrochemical Properties of Two New Asymmetric Tetrathiafulvalene Derivatives
文章编号:
1001-4616(2013)02-0061-06
作者:
张 睿
扬州职业大学,江苏 扬州 225009
Author(s):
Zhang Rui
Yangzhou Polytechnic College,Yangzhou 225009,China
关键词:
四硫富瓦烯(TTF)不对称偶联晶体结构循环伏安
Keywords:
tetrathiafulvalene(TTF)unsymmetrical couplingcrystal structurecyclic voltammetry
分类号:
O6
文献标志码:
A
摘要:
以1,3-甲基二硫基-二硫醇-2-硫酮(化合物1)和1,3-环戊烯二硫基-二硫醇-2-硫酮(化合物5)为原料,在P(OEt)3存在下,分别与1,3-二(氰乙硫基)-二硫醇-2-氧酮(化合物3)发生不对称偶联,得到了两个新型的不对称四硫富瓦烯衍生物(化合物6a和6b).对二者进行了熔点、IR、1H NMR、13C NMR、MS、EA等表征,解析了其晶体结构,并对它们的电化学行为做了初步的研究.
Abstract:
We designed and synthesized two new asymmetric tetrathiafulvalene derivatives(compound 6a and 6b)with 1,3-(methyldithio)-dithiole-2-thione(compound 1)and 1,3-(cyclopentodithio)-dithiole-2-thione(compound 5),asymmetricly couples with 1,3-bis(cyanoethylethio)-dithiole-2-one(compound 3)in P(OEt)3 respectively.Also we characterized them by melting points、IR、1H NMR、13C NMR、MS、EA and introduced their crystal strcture and electrochemical properties.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2012-09-10.
基金项目:扬州职业大学“‘应用化工技术’校经教改试点专业”项目.
通讯联系人:张睿,讲师,研究方向:有机合成及化学化工教学.E-mail:z.tulip@163.com
更新日期/Last Update: 2013-06-30