[1]黄艳超,武雪芳,周羽化,等.水环境中锑污染及其修复技术研究进展[J].南京师范大学学报(自然科学版),2015,38(04):122.
 Huang Yanchao,Wu Xuefang,Zhou Yuhua,et al.Research Progress of Antimony Contamination in WaterEnvironment and Remediation Techniques[J].Journal of Nanjing Normal University(Natural Science Edition),2015,38(04):122.
点击复制

水环境中锑污染及其修复技术研究进展()
分享到:

《南京师范大学学报》(自然科学版)[ISSN:1001-4616/CN:32-1239/N]

卷:
第38卷
期数:
2015年04期
页码:
122
栏目:
地理学
出版日期:
2015-12-30

文章信息/Info

Title:
Research Progress of Antimony Contamination in WaterEnvironment and Remediation Techniques
作者:
黄艳超武雪芳周羽化卢延娜王宗爽
中国环境科学研究院,北京 100012
Author(s):
Huang YanchaoWu XuefangZhou YuhuaLu YannaWang Zongshuang
Chinese Research Academy of Environmental Sciences,Beijing 100012,China
关键词:
锑污染修复技术水环境
Keywords:
antimony contaminationremediation techniquewater environment
分类号:
X52
文献标志码:
A
摘要:
锑是一种具有毒性和潜在致癌性的金属元素. 作为锑的主要产出国,我国锑开采和冶炼区周围水环境中的锑污染问题日益严重. 环境中的锑能通过直接或间接的途径进入到人体,从而危害人体健康. 本文概述了锑在水环境中的存在形态和化学行为,总结了目前各国水环境中锑污染现状和主要修复方法的研究进展,并对未来锑研究的方向进行了展望.
Abstract:
Antimony(Sb)is a kind of trace metal element with potential carcinogenicity. Due to Sb mining and smelting processes,large quantities of Sb have been released resulting in serious Sb contamination of the local water environments. Antimony enters into the human body while breathing air,drinking water or eating foods,or merely contacting with the substances which contain antimony. This paper reviews some researches on the distribution,speciation,contamination status and remediation techniques of antimony in water environment and points out the direction for future research.

参考文献/References:

[1]FILELLA M,BELZILE N,CHEN Y W. Antimony in the environment:a review focused on natural watersⅠ. Occurrence[J]. Earth-science review,2002,57(1/2):125-176.
[2]FILELLA M,BELZILE N,CHEN Y W. Antimony in the environment:a review focused on natural waters Ⅱ. Relevant solution chemistry[J]. Earth-science review,2002,59(1/2/3/4):265-285.
[3]UNITED STATES ENVIRONMENTAL PROTECTION AGENCY. National primary drinking water standards[S/OL]. [2014-09-20]. http://water.epa.gov/drink/contaminants/index.cfm.
[4]COUNCIL OF THE EUROPEAN UNION. Council directive 98r83rEC of 3 November 1998 on the quality of water intended for human consumption[J]. Official journal of the European communities,1998,330:32-54.
[5]UNITED NATIONS ENVIRONMENTAL PROGRAM. Basel convention on the control of transboundary movements of hazardous wastes and their disposal[M/OL]. [2014-09-16]. http://legal.un.org/avl/ha/bcctmhwd/bcctmhwd.html.
[6]KOLJONEN T. Geochemical atlas of Finland. Part 2:till[M]. Espoo:Geological Survey of Finland,1992:214-224.
[7]SALMINEN R,BATISTA M J,BIDOVEC M,et al. Geochemical atlas of Europe. Part 1:background information,methodology and maps[M]. Espoo:Geological Survey of Finland,2005:157-162.
[8]BIRKE M,RAUCH U,RASCHKA H,et al. Geochemischer atlas der bundesrepublik deutschland[M]. Hannover:Bundesanstalt Für Geowissenschaften Und Rohstoffe,2006:214-217.
[9]曹秀红. 长江流域、黄河口以及邻近海域溶解态砷、硒、锑的分布、季节变化及影响因素[D]. 青岛:中国海洋大学,2012.
[10]REIMANN C,MATSCHULLAT J,BIRKE M,et al. Antimony in the environment:lessons from geochemical mapping[J]. Applied geochemistry,2010,25(2):175-198.
[11]LIDE D R. CRC handbook of chemistry and physics[M]. Boca Raton:CRC Press,1996:141-143.
[12]DONAT J R,BRULAND K W. Trace elements in the ocean[M]. Boca Raton:CRC Press,1995:247-281.
[13]CUTTER G A,CUTTER L S,FEATHERSTONE A M,et al. Antimony and arsenic biogeochemistry in the western Atlantic Ocean[J]. Deep-sea research Ⅱ,2001(48):2 895-2 915.
[14]万玉霞. 天然水体中锑的分析方法及其在黄河口和黄海的分布[D]. 青岛:中国海洋大学,2010.
[15]FRENGSTAD B,MIDTG?RD A K,BANKS D,et al. The chemistry of Norwegian groundwaters Ⅲ. The distribution of trace elements in 476 crystalline bedrock groundwaters,as analysed by ICP-MS techniques[J]. Science of the total environment,2000,246(1):21-40.
[16]LAHERMO P,TARVAINEN T,HATAKKA T,et al. One thousand wells-the physical-chemical quality of finnish well waters in 1999[M]. Espoo:Geological Survey of Finland,2002:257-261.
[17]REIMANN C,BJORVATN K,FRENGSTAD B,et al. Drinking water quality in the Ethiopian section of the East African Rift ValleyⅠ:data and health aspects[J]. Science of the total environment,2003,311(1/2/3):65-80.
[18]SUN Y C,YANG J Y. Simultaneous determination of arsenic(Ⅲ,Ⅴ),selenium(Ⅳ,Ⅵ),and antimony(Ⅲ,Ⅴ)in natural water by coprecipitation and neutron activation analysis[J]. Analytica chimica acta,1999,395(3):293-300.
[19]DENG T L,CHEN Y W,BELZILE N. Antimony speciation at ultra trace levels using hydride generation atomic fluorescence spectrometry and 8-hydroxyquinoline as an efficient masking agent[J]. Analytica chimica acta,2001,432(2):293-302.
[20]SUN Y C,YANG J Y,LIN Y F,et al. Determination of antimony(Ⅲ,Ⅴ)in natural waters by coprecipitation and neutron activation analysis[J]. Analytica chimica acta,1993,276(1):33-37.
[21]INDEX MUNDI. Antimony:world mine production,by country[J/OL]. [2014-08-20]. http://www.indexmundi.com/en/commodities/minerals/antimony/antimony_t9.html.
[22]HE M,WANG X,WU F,et al. Antimony pollution in China[J]. Science of the total environment,2012,421/422(3):41-50.
[23]朱静,吴丰昌,邓秋静,等. 湖南锡矿山周边水体的环境特征[J]. 环境科学学报,2009,29(2):655-661.
[24]FU Z,WU F,AMARASIRIWARDENA D,et al. Antimony,arsenic and mercury in the aquatic environment and fish in a large antimony mining area in Hunan,China[J]. Science of the total environment,2010,408(16):3 403-3 410.
[25]WHO. Guidelines for drinking-water quality[S/OL]. [2014-08-20]. http://www.who.int/water_sanitation_health/publications/dwq_guidelines/en/.
[26]FU Z,WU F,MO C,et al. Bioaccumulation of antimony,arsenic,and mercury in the vicinities of a large antimony mine,China[J]. Microchemical journal,2011,97(1):12-19.
[27]卢莎莎,顾尚义,韩露,等. 都柳江水体-沉积物间锑的迁移转化规律[J]. 贵州大学学报(自然科学版),2013,30(3):131-136.
[28]李雪华. 锑矿区沉积物生态风险评价及修复技术研究[D]. 北京:北京林业大学,2013.
[29]CIDU R,BIDDAU R,DORE E,et al. Antimony in the soil-water-plant system at the Su Suergiu abandoned mine(Sardinia,Italy):strategies to mitigate contamination[J]. Science of the total environment,2014,497/498(8):319-331.
[30]HILLER E,LALINSKá B,CHOVAN M,et al. Arsenic and antimony contamination of waters,stream sediments and soils in the vicinity of abandoned antimony mines in the Western Carpathians,Slovakia[J]. Applied geochemistry,2012,27(3):598-614.
[31]WILSON N J,CRAW S,HUNTER K. Contributions of discharges from a historic antimony mine to metalloid content of river waters,Marlborough,New Zealand[J]. Journal of geochemical exploration,2004,84(3):127-139.
[32] RITCHIE V J,ILGEN A G,MULLER S H,et al. Mobility and chemical fate of antimony and arsenic in historic mining environments of the Kantishna Hills District,Denali National Park and Preserve,Alaska[J]. Chemical geology,2013,335:172-188.
[33] MARIUSSEN E,LJ?NES M,STR?MSENG A E. Use of sorbents for purification of lead,copper and antimony in runoff water from small arms shooting ranges[J]. Journal of hazardous materials,2012,243:95-104.
[34] KLEIN D H,ANDREN A W,BOLTON N E. Trace element discharges from coal combustion for power production[J]. Water,air and soil pollution,1975,5(1):71-77.
[35] 邱罡,吴双桃,陈少瑾. 水浮莲干体吸附去除水中的锑(Ⅲ)[J]. 环境工程学报,2012,6(8):2 683-2 688.
[36] IQBAL M,SAEED A,EDYVEAN R G J. Bioremoval of antimony(Ⅲ)from contaminated water using several plant wastes:optimization of batch and dynamic flow conditions for sorption by green bean husk(vigna radiata)[J]. Chemical engineering journal,2013,225:192-201.
[37] WU F,SUN F,WU S,et al. Removal of antimony(Ⅲ)from aqueous solution by freshwater cyanobacteria microcystis biomass[J]. Chemical engineering journal,2012,183:172-179.
[38] SALAM M A,MOHAMED R M. Removal of antimony(Ⅲ)by multi-walled carbon nanotubes from model solution and environmental samples[J]. Chemical engineering research and design,2013,91(7):1 352-1 360.
[39] LENG Y,GUO W,SU S,et al. Removal of antimony(Ⅲ)from aqueous solution by graphene as an adsorbent[J]. Chemical engineering journal,2012,211/212:406-411.
[40] LI X,DOU X,LI J. Antimony(Ⅴ)removal from water by iron-zirconium bimetal oxide:performance and mechanism[J]. Journal of environmental science,2012,24(7):1 197-1 203.
[41] 刘峰,刘锐平,刘会娟,等. 铁锰复合氧化物同时吸附锑镉性能研究[J]. 环境科学学报,2013,33(12):3 189-3 196.
[42] XU W,WANG H,LIU R,et al. The mechanism of antimony(Ⅲ)removal and its reactions on the surfaces of Fe-Mn binary oxide[J]. Journal of colloid and interface science,2011,363(1):320-326.
[43] 叶鸣,曾嵘,张先斌,等. 锰改性石英砂的表征及其对水中三价锑的吸附性能初探[J]. 广东化学,2013,41(16):44-46.
[44] 李双双,戴友芝,李娜,等. 铁改性海泡石的研制及吸附锑特性[J]. 水处理技术,2009,35(5):49-52.
[45] Guo X,Wu Z,He M,et al. Adsorption of antimony onto iron oxyhydroxides:adsorption behavior and surface structure[J]. Journal of hazardous materials,2014,276:339-345.
[46] MIAO Y,HAN F,PAN B,et al. Antimony(V)removal from water by hydrated ferric oxides supported by calcite sand and polymeric anion exchanger[J]. Journal of environmental sciences,2014,26(2):307-314.
[47] 李双双,戴友芝,罗春香,等. 锑在水中的形态变化及除锑技术现状[J]. 化工环保,2009,29(2):131-134.
[48] DU X,QU F,LIANG H,et al. Removal of antimony(Ⅲ)from polluted surface water using a hybrid coagulation-flocculation-ultrafiltration(CF-UF)process[J]. Chemical engineering journal,2014,254:293-301.
[49] GUO X,WU Z,HE M. Removal of antimony(Ⅴ)and antimony(Ⅲ)from drinking water by coagulation-flocculation-sedimentation(CFS)[J]. Water research,2009,43(7):4 327-4 335.
[50] ZHU J,WU F,PAN X,et al. Removal of antimony from antimony mine flotation wastewater by electrocoagulation with aluminum electrodes[J]. Journal of environmental sciences,2011,23(7):1 066-1 071.
[51] 吴丰昌,朱静. 用铁电极-电絮凝法处理含锑工业废水的方法:CN101781042A[P]. 2010-07-21.
[52] 张家兴,王超,杨波,等. 电混凝去除水中锑污染物[J]. 环境工程学报,2014,8(10):4 244-4 248.

备注/Memo

备注/Memo:
收稿日期:2014-11-21. 
基金项目:环保部公益性项目(201209052). 
通讯联系人:黄艳超,博士,助理研究员,研究方向:土壤-植物体系重金属污染和污染场地修复等. E-mail:hyc_gucas@163.com
更新日期/Last Update: 2015-12-30