[1]陆晓赟,任家丰,孙 婧,等.电催化还原处理硝酸盐的电极材料研究进展[J].南京师大学报(自然科学版),2021,44(02):134-140.[doi:10.3969/j.issn.1001-4616.2021.02.019]
　Lu Xiaoyun,Ren Jiafeng,Sun Jing,et al.Research Progress of Electrode Materials forElectrocatalytic Reduction of Nitrate[J].Journal of Nanjing Normal University(Natural Science Edition),2021,44(02):134-140.[doi:10.3969/j.issn.1001-4616.2021.02.019]
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电催化还原处理硝酸盐的电极材料研究进展()
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《南京师大学报（自然科学版）》[ISSN:1001-4616/CN:32-1239/N]

卷:
第44卷
期数:
2021年02期
页码:
134-140
栏目:
·环境科学与工程·
出版日期:
2021-06-30

文章信息/Info

Title:
Research Progress of Electrode Materials forElectrocatalytic Reduction of Nitrate
文章编号:
1001-4616(2021)02-0134-07
作者:
陆晓赟; 任家丰; 孙 婧; 李洪祥; 李 云; 张利民; 何 欢; 宋海欧
南京师范大学环境学院,江苏 南京 210023
Author(s):
Lu Xiaoyun; Ren Jiafeng; Sun Jing; Li Hongxiang; Li Yun; Zhang Limin; He Huan; Song Haiou
School of Environment,Nanjing Normal University,Nanjing 210023,China
关键词:
硝酸盐还原; 电催化; 电极材料; 水处理
Keywords:
nitrate reduction; electrocatalysis; electrode materials; water treatment
分类号:
O646.541
DOI:
10.3969/j.issn.1001-4616.2021.02.019
文献标志码:
A
摘要:
地下水和地表水的硝酸盐污染日益严重,威胁着人类健康和生态系统,已成为亟待解决的环境问题之一. 电催化还原作为一种绿色环保、无二次污染的技术,能够将硝酸盐转化为无毒无害的氮气,具有良好的应用前景. 在电催化还原硝酸盐体系当中,电极材料是电化学反应的关键,在过去几十年里,许多学者在设计和制备高效的电极方面做了大量研究. 本文介绍了电催化还原处理硝酸盐技术的基本原理和降解路径,重点讨论了国内外电催化还原处理硝酸盐所用的不同电极材料,总结了不同电极材料的应用现状,并对电催化还原硝酸盐技术未来的发展方向提出了展望.
Abstract:
The nitrate pollution of groundwater and surface water is becoming more and more serious,which threatens human health and ecosystem,and has become one of the environmental problems to be solved urgently. Electrocatalytic reduction as a kind of green environmental protection technology,no secondary pollution to convert nitrate into non-toxic harmless nitrogen gas,has a good application prospect. In the electrocatalytic reduction of nitrate system,electrode material is the key to the electrochemical reaction. In the past decades,many scholars have done a lot of research on the design and preparation of efficient electrode. In this paper,the basic principle and degradation path of electrocatalytic reduction of nitrate are introduced,and the different electrode materials used in electrocatalytic reduction of nitrate at home and abroad are emphatically discussed. The application status of different electrode materials is summarized,and the development direction of electrocatalytic reduction of nitrate in the future is prospected.

参考文献/References:

[1] MARTíNEZ J,ORTIZ A,ORTIZ I. State-of-the-art and perspectives of the catalytic and electrocatalytic reduction of aqueous nitrates[J]. Applied catalysis B:environmental,2017,207:42-59.
[2]ROSCA V,DUCA M,DE GROOT M T,et al. Nitrogen cycle electrocatalysis[J]. Chemical reviews,2009,109(6):2209-2244.
[3]COMER B M,FUENTES P,DIMKPA C O,et al. Prospects and challenges for solar fertilizers[J]. Joule,2019,3(7):1578-1605.
[4]FERNáNDEZ N Y,MARA?N E,SOONS J,et al. Denitrification of wastewater containing high nitrate and calcium concentrations[J]. Bioresource technology,2008,99(17):7976-7981.
[5]SOBTI R C,SHARMA S K. Nitrate removal from ground water[J]. E-journal of chemistry,2011,9(4):1667-1675.
[6]GHAFARI S,HASAN M,AROUA M K. Bio-electrochemical removal of nitrate from water and wastewater:a review[J]. Bioresource technology,2008,99(10):3965-3974.
[7]TUGAOEN H O,GARCIA S S,HRISTOVSKI K,et al. Challenges in photocatalytic reduction of nitrate as a water treatment technology[J]. Science of the total environment,2017,599/600:1524-1551.
[8]中华人民共和国卫生部,国家标准化管理委员会. 生活饮用水卫生标准:GB5749—2006[S]. 北京:中国标准出版社,2007.
[9]SAMATYA S,KABAY N,YUEKSEL U,et al. Removal of nitrate from aqueous solution by nitrate selective ion exchange resins[J]. Reactive & functional polymers,2006,66(11):1206-1214.
[10]BARRABéS N,Sá J. Catalytic nitrate removal from water,past,present and future perspectives[J]. Applied catalysis B:environmental,2011,104:1-5.
[11]WANG L L. Mechanism and effectiveness of Ti-based nano-electrode for electrochemical denitrification[J]. International journal of electrochemical science,2017,12(3):1992-2002.
[12]PAIDAR M,ROUAR I,BOUZEK K. Electrochemical removal of nitrate ions in waste solutions after regeneration of ion exchange columns[J]. Journal of applied electrochemistry,1999,29(5):611-617.
[13]REYTER D,BéLANGER D,ROUé L. Study of the electroreduction of nitrate on copper in alkaline solution[J]. Electrochimica acta,2008,53:5977-5984.
[14]VOOYS A C A D,SANTEN R A V,VEEN J A R V. Electrocatalytic reduction of NO-3 on palladium/copper electrodes[J]. Journal of molecular catalysis A:chemical,2000,154(1/2):203-215.
[15]HUPERT M,MUCK A,WANG J,et al. Conductive diamond thin-films in electrochemistry[J]. Diamond & related materials,2003,12(10/11):1940-1949.
[16]BUTCHER J D P,GEWIRTH A A. Nitrate reduction pathways on Cu single crystal surfaces:effect of oxide and Cl-[J]. Nano energy,2016,29:457-465.
[17]HOSSAIN M M,NAKATA K,KAWAGUCHI T,et al. Reduction of nitrate on electrochemically pre-reduced tin-modified palladium electrodes[J]. Journal of electroanalytical chemistry,2013,707:59-65.
[18]JIANG C J,LIU L F,CRITTENDEN J C. An electrochemical process that uses an Fe0/TiO2 cathode to degrade typical dyes and antibiotics and a bio-anode that produces electricity[J]. Frontiers of environmental science & engineering,2016,10(4):15.1-15.8.
[19]LACASA E,CANIZARES P,LIANOS J,et al. Effect of the cathode material on the removal of nitrates by electrolysis in non-chloride media[J]. Journal of hazardous materials,2012,213/214:478-484.
[20]DING J,LI W,ZHAO Q L,et al. Electroreduction of nitrate in water:role of cathode and cell configuration[J]. Chemical engineering journal,2015,271:252-259.
[21]GARCíA G C,DROGUI P,ZAVISKA F,et al. Experimental design methodology applied to electrochemical oxidation of carbamazepine using Ti/PbO2 and Ti/BDD electrodes[J]. Journal of electroanalytical chemistry,2014,732:1-10.
[22]ZHANG X,WANG Y T,LIU C B,et al. Recent advances in non-noble metal electrocatalysts for nitrate reduction[J]. Chemical engineering journal,2021,403:126269.1-126269.16.
[23]MOSER J,BARREIRO A,BACHTOLD A. Current-induced cleaning of graphene[J]. Applied physics letters,2007,91(16):163513.1-163513.3.
[24]MITOV M,CHORBADZHIYSKA E,NALBANDIAN L,et al. Nickel-based electrodeposits as potential cathode catalysts for hydrogen production by microbial electrolysis[J]. Journal of power sources,2017,356:467-472.
[25]WANG Q F,ZHAO X B,ZHANG J F,et al. Investigation of nitrate reduction on polycrystalline Pt nanoparticles with controlled crystal plane[J]. Journal of electroanalytical chemistry,2015,755:210-214.
[26]MATTAROZZI L,CATTARIN S,COMISSO N,et al. Electrodeposition of compact and porous Cu-Pd alloy layers and their application to nitrate reduction in alkali[J]. Electrochimica acta,2017,230:365-372.
[27]DORTSIOU M,KATSOUNAROS I,POLATIDES C,et al. Influence of the electrode and the pH on the rate and the product distribution of the electrochemical removal of nitrate[J]. Environmental technology,2013,34(1/4):373-381.
[28]LI M,FENG C P,ZHANG Z Y,et al. Efficient electrochemical reduction of nitrate to nitrogen using Ti/IrO2-Pt anode and different cathodes[J]. Electrochimica acta,2009,54:4600-4606.
[29]REYTER D,BéLANGER D,ROUé L. Nitrate removal by a paired electrolysis on copper and Ti/IrO2 coupled electrodes-influence of the anode/cathode surface area ratio[J]. Water research,2010,44:1918-1926.
[30]REYTER D,CHAMOULAUD G,BéLANGER D,et al. Electrocatalytic reduction of nitrate on copper electrodes prepared by high-energy ball milling[J]. Journal of electroanalytical chemistry,2006,596:13-24.
[31]PéREZ G E,FIGUEIREDO M C,KATSOUNAROS I,et al. Electrocatalytic reduction of nitrate on copper single crystals in acidic and alkaline solutions[J]. Electrochimica acta,2017,227:77-84.
[32]ANASTASOPOULOS A,HANNAH L,HAYDEN B E. High throughput optimisation of PdCu alloy electrocatalysts for the reduction of nitrate ions[J]. Journal of catalysis,2013,305:27-35.
[33]SOARES O S G P,óRFAO J J M,PEREIRA M F R. Nitrate reduction with hydrogen in the presence of physical mixtures with mono and bimetallic catalysts and ions in solution[J]. Applied catalysis B:environmental,2011,102:424-432.
[34]BIRDJA Y Y,YANG J,KOPER M T M. Electrocatalytic reduction of nitrate on tin-modified palladium electrodes[J]. Electrochimica acta,2014,140:518-524.
[35]SHIH Y J,WU Z L,HUANG Y H,et al. Electrochemical nitrate reduction as affected by the crystal morphology and facet of copper nanoparticles supported on nickel foam electrodes(Cu/Ni)[J]. Chemical engineering journal,2020,383:123157.1-123157.11.
[36]WANG Q,HUANG H,WANG L C,et al. Electrochemical removal of nitrate by Cu/Ti electrode coupled with copper-modified activated carbon particles at a low current density[J]. Environmental science and pollution research,2019,26(17):17567-17576.
[37]ZHANG Y M,ZHAO Y L,CHEN Z,et al. Electrochemical reduction of nitrate via Cu/Ni composite cathode paired with Ir-Ru/Ti anode:high efficiency and N2 selectivity[J]. Electrochimica acta,2018,291:151-160.
[38]GAO W C,GAO L L,LI D,et al. Removal of nitrate from water by the electrocatalytic denitrification on the Cu-Bi electrode[J]. Journal of electroanalytical chemistry,2018,817:202-209.
[39]ZHANG L H,YIN D,ZHAI S Y,et al. Electrochemical behaviors and influence factors of copper and copper alloys cathode for electrocatalytic nitrate removal[J]. Water environment research,2019,91(12):1589-1599.
[40]SU J F,KUAN W F,LIU H J,et al. Mode of electrochemical deposition on the structure and morphology of bimetallic electrodes and its effect on nitrate reduction toward nitrogen selectivity[J]. Applied catalysis B:environmental,2019,257:117909.1-117909.10.
[41]KIM D E,PAK D. Ti plate with TiO2 nanotube arrays as a novel cathode for nitrate reduction[J]. Chemosphere,2019,228:611-618.
[42]SU L H,LI K,ZHANG H B,et al. Electrochemical nitrate reduction by using a novel Co3O4/Ti cathode[J]. Water research,2017,120:1-11.
[43]LI W,XIAO C W,ZHAO Y,et al. Electrochemical reduction of high-concentrated nitrate using Ti/TiO2 nanotube array anode and Fe cathode in dual-chamber cell[J]. Catalysis letters,2016,146(12):2585-2595.
[44]JONOUSH Z A,REZAEE A,GHAFFARINEJAD A. Electrocatalytic nitrate reduction using Fe0/Fe3O4 nanoparticles immobilized on nickel foam:selectivity and energy consumption studies[J]. Journal of cleaner production,2020,242:118569.1-118569.12.
[45]YIN D,LIU Y Y,SONG P F,et al. In situ growth of copper/reduced graphene oxide on graphite surfaces for the electrocatalytic reduction of nitrate[J]. Electrochimica acta,2019,324:134846.1-134846.9.
[46]MA X J,LI M,LIU X,et al. A graphene oxide nanosheet-modified Ti nanocomposite electrode with enhanced electrochemical property and stability for nitrate reduction[J]. Chemical engineering journal,2018,348:171-179.
[47]?NüLüER T,?DURAK B,DOAGˇG1AN H ? Electrochemical reduction of nitrate on graphene modified copper electrodes in alkaline media[J]. Journal of electroanalytical chemistry,2013,699:1-5.
[48]WANG J H,WANG S,ZHANG Z,et al. Preparation of Cu/GO/Ti electrode by electrodeposition and its enhanced electrochemical reduction for aqueous nitrate[J]. Journal of environmental management,2020,276:111357.1-111357.7.
[49]GAO J N,JIANG B,NI C C,et al. Enhanced reduction of nitrate by noble metal-free electrocatalysis on P doped three-dimensional Co3O4 cathode:mechanism exploration from both experimental and DFT studies[J]. Chemical engineering journal,2020,382:123034.1-123034.10.

备注/Memo

备注/Memo:
收稿日期:2021-01-11.
基金项目:国家自然科学基金项目(51408297、51778281、41877336)、污染控制与资源化重点实验室基金项目(PCRRF19032、 PCRRF18018)、南京师范大学基金项目(184080H202B146).
通讯作者:宋海欧,博士,教授,研究方向:光电化学方法对毒害污染物的去除与资源化. E-mail:songhaiou2011@126.com
更新日期/Last Update: 2021-06-30