[1]包富荣,季春,卢珊,等.可溶性酞菁化合物的溶剂效应[J].南京师大学报(自然科学版),2007,30(03):58-63.
 Bao Furong,Ji Chun,Lu Shan,et al.Solvent Effects of Soluble Phthalocyanines[J].Journal of Nanjing Normal University(Natural Science Edition),2007,30(03):58-63.
点击复制

可溶性酞菁化合物的溶剂效应()
分享到:

《南京师大学报(自然科学版)》[ISSN:1001-4616/CN:32-1239/N]

卷:
第30卷
期数:
2007年03期
页码:
58-63
栏目:
化学
出版日期:
2007-09-30

文章信息/Info

Title:
Solvent Effects of Soluble Phthalocyanines
作者:
包富荣;季春;卢珊;魏少华;周宁琳;李利;沈健;
南京师范大学化学与环境科学学院,江苏省生物医药功能材料工程研究中心,江苏南京210097
Author(s):
Bao FurongJi ChunLu ShanWei ShaohuaZhou NinglinLi LiShen Jian
School of Chemistry and Environmental Science,Nanjing Normal University,Jiangsu Engineering Research Center of Bio-medical Function Materials,Nanjing 210097,China
关键词:
酞菁 溶剂效应 吸收光谱 聚集
Keywords:
phthalocyanines solvent effects absorp tion spectra aggregate
分类号:
O621.2
摘要:
通过对所合成的9个可溶性酞菁衍生物在13种不同性质溶剂中吸收光谱的研究,发现其最大吸收波长的波数ν与f(n,ε)具有良好的线性相关性,表明化合物λm ax的位移变化主要由与溶剂折射率n相关的Bayliss函数项所决定,且与溶剂的介电常数ε有关;忽略酞菁分子之间的相互作用(即聚集的影响)以及溶剂的配位能力,是引起模型线性相关性偏差的主要原因.
Abstract:
The results of UV absorp tion spectroscopy of nine soluble phthalocyanines in thirteen solvents indicated that there is good linearity between theνof theλmax and f ( n, ε) , so the change ofλmax are de termined by the Bayliss function which is correlatingwith the refractive index and the dielectric constant of the solvent. In addition, the interaction among the molecules of phthalocyanines and the coordination abil ity of solventswere the main cause of the calculation error

参考文献/References:

[ 1 ]  Arthur L Thoms. Phthalocyanine Research and App lications[M ]. London, UK: CRC Press Inc, 1994.
[ 2 ]  Suzette A Priola, Anne Raines, Winslow S Caughey. Porphyrin and phthalocyanine antiscrap ie compounds [ J ]. Science,2000, 287: 1 503-1 506.
[ 3 ]  魏少华,黄德音,韩莉. 可溶性镍酞菁的光谱特性研究[ J ]. 感光科学与光化学, 2002, 20 (6) : 411-416.
[ 4 ]  Gao L indong, Qian Xuehong. Absorp tion and p luorescence spectral p roperties of tetra ( fluoroalkoxy) metallophthalocyanines
[ J ]. Dyes and Pigments, 2001, 51 (1) : 51255.
[ 5 ]  魏少华,黄德音. 四异丁氧基镍酞菁的合成及其溶剂效应[ J ]. 精细化工, 2002, 19 (10) : 581-583.
[ 6 ]  Bayliss N S, Mcrae E G. Solvent effects in organic spectra: dipole forces and the Frank2Condon p rincip le[ J ]. J Phys Chem,1954, 58: 1 00221 006.
[ 7 ]  NicolM. Solvent effects on electronic spectra[ J ]. App l Spectrosc Rev, 1974, 8 (2) : 183-192.
[ 8 ]  Wei Shaohua, Zhou J iahong, Huang Deyin, et al. Synthesis and TypeⅠ/TypeⅡ photosensitizing p roperties of a novel am-phiphilic zinc phthalocyanine[ J ]. Dyes and Pigments, 2006, 71 (1) : 61-67.
[ 9 ]  Wei Shaohua, Huang Deyin, L i L i, et al. Synthesis and p roperties of some novel soluble metallophthalocyanines containing 32trifluromethylphenyoxymoiety[ J ]. Dyes and Pigments, 2003, 56 (1) : 1-6.
[ 10 ]  WestA, Geddes A L. The effect of solvents and of solid substrates on the visible molecular absorp tion spectrum of cyaninedyes[ J ]. J Phys Chem, 1964, 68 (4) : 8372844.
[ 11 ]  唐福龙,顾冬红,朱从善,等. 可溶性钒氧酞菁在不同介质中的吸收光谱研究[J ]. 光学学报, 1997, 17 (10) : 1 450-1 456.
[ 12 ]  黄剑东,刘尔生,杨素苓,等. 某些金属酞菁配合物的电子吸收光谱和荧光光谱[ J ]. 光谱学与光谱分析, 2000,20 (1) : 95-97.

相似文献/References:

[1]戴冬萍,等.p-HPcZn-SiO2纳米粒的制备与表征[J].南京师大学报(自然科学版),2009,32(01):87.
 Dai Dongping,Zhou Lin,Jiang Weiwei,et al.Preparation and Characterization of p-HPcZn-SiO2[J].Journal of Nanjing Normal University(Natural Science Edition),2009,32(03):87.
[2]沈珠英,陈维,沈永淼,等.溶剂效应对中氮茚荧光性质的影响[J].南京师大学报(自然科学版),2005,28(01):58.
 Shen Zhuying~.Solvent affection on the Fluorescence properties of Indolizines[J].Journal of Nanjing Normal University(Natural Science Edition),2005,28(03):58.
[3]王崇侠,余忠清,顾晓天,等.溶剂对二(2-苯基-8-羟基喹啉)锌的荧光性质的影响[J].南京师大学报(自然科学版),2004,27(01):55.
 Wang Chongxia~,Yu Zhongqing~,Gu Xiaotian~,et al.Solvent affection on the Fluorescence properties of Bis(2-phenyl-8-hydroxyquinolato) Zinc[J].Journal of Nanjing Normal University(Natural Science Edition),2004,27(03):55.
[4]王 越,王 傲,周 林,等.LSPcZn与马心肌红蛋白相互作用的研究[J].南京师大学报(自然科学版),2016,39(02):28.[doi:10.3969/j.issn.1001-4616.2016.02.006]
 Wang Yue,Wang Ao,Zhou Lin,et al.Interaction of LSPcZn and Myoglobin[J].Journal of Nanjing Normal University(Natural Science Edition),2016,39(03):28.[doi:10.3969/j.issn.1001-4616.2016.02.006]

备注/Memo

备注/Memo:
基金项目:国家自然科学基金(20673058) 、江苏省自然科学基金(BK2006216) 、江苏省教育厅自然科学基金(06KJB150053)资助项目.
作者简介:包富荣(1982—) ,女,硕士研究生,主要从事有机光化学和光谱分析的学习与研究. E-mail: frbao@163. com
通讯联系人:魏少华, 1964—,博士,副教授, 主要从事有机光化学和功能材料的教学与研究. E-mail: shwei@njnu. edu. cn
更新日期/Last Update: 2013-05-05