[1]余伊丽,唐 剑,应椰琦,等.光催化的含吸电子基团卤代苯的偶联反应[J].南京师大学报(自然科学版),2014,37(02):75.
 Yu Yili,Tang Jian,Ying Yeqi,et al.Photocatalytic Coupling Reactions of Halobenzenes With an Electron Withdrawing Group[J].Journal of Nanjing Normal University(Natural Science Edition),2014,37(02):75.
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光催化的含吸电子基团卤代苯的偶联反应()
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《南京师大学报(自然科学版)》[ISSN:1001-4616/CN:32-1239/N]

卷:
第37卷
期数:
2014年02期
页码:
75
栏目:
化学
出版日期:
2014-06-30

文章信息/Info

Title:
Photocatalytic Coupling Reactions of Halobenzenes With an Electron Withdrawing Group
作者:
余伊丽1唐 剑12应椰琦1黄蒙蒙1程 洁1沈祥茹1沈永淼1
(1. 绍兴文理学院化学化工学院,浙江绍兴312000) (2. 南京师范大学化学与材料科学学院,江苏南京210023)
Author(s):
Yu Yili1Tang Jian12Ying Yeqi1Huang Mengmeng1Cheng Jie1Shen Xiangru1Shen Yongmiao1
(1. School of Chemistry and Chemical Engineering,Shaoxing University,Shaoxing 312000,China) (2. School of Chemistry and Materials Science,Nanjing Normal University,Nanjing 210023,China)
关键词:
吸电子基团卤代苯光催化偶联反应
Keywords:
electron withdrawing grouphalobenzenephotocatalyticcoupling reaction
分类号:
O625. 21
文献标志码:
A
摘要:
通过含酯基或酰基吸电子基团的溴苯或碘苯和苯衍生物(苯、甲苯、二甲苯,二苯基甲醚)的光催化偶联反应合成了一系列联苯衍生物,研究了光催化脱卤化氢偶联反应的最佳反应条件,并讨论了取代基对产率的影响.
Abstract:
A series of biphenyl derivatives were synthesized by photocatalytic reactions of benzene derivatives(benzene, toluene,1,4-dimethylbenzene, oxydibenzene) with halobenzene which contains an electron withdrawing group ( Ester group,Acyl group). The optimal conditions for this dehydrohalogenative coupling reaction were determined and the influence of substituents on the yields were also discussed.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2013-02-22.
基金项目:浙江省大学生科技创新活动计划(新苗人才计划)、浙江省自然科学基金(Y4080395).
通讯联系人:沈永淼,副教授,研究方向:有机合成及有机光化学. E-mail:shenyongmiao@usx.edu.cn
更新日期/Last Update: 2014-06-30