[1]江玉亮,马振毛,杨安博,等.N-Cycl[3,2,2]azine甲酰脲衍生物对金属离子的选择性研究[J].南京师大学报(自然科学版),2012,35(01):63-65.
 Jiang Yuliang,Ma Zhenmao,Yang Anbo,et al.Synthesis of N-Cyclazine Formyl Urea Derivatives and Studies on Its Recognizing Properties on Metal Ions[J].Journal of Nanjing Normal University(Natural Science Edition),2012,35(01):63-65.
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N-Cycl[3,2,2]azine甲酰脲衍生物对金属离子的选择性研究()
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《南京师大学报(自然科学版)》[ISSN:1001-4616/CN:32-1239/N]

卷:
第35卷
期数:
2012年01期
页码:
63-65
栏目:
化学
出版日期:
2012-03-20

文章信息/Info

Title:
Synthesis of N-Cyclazine Formyl Urea Derivatives and Studies on Its Recognizing Properties on Metal Ions
作者:
江玉亮;马振毛;杨安博;陈长信;
南京师范大学化学与材料科学学院,江苏南京210097
Author(s):
Jiang YuliangMa ZhenmaoYang AnboChen Changxin
School of Chemistry and Materials Science,Nanjing 210097,China
关键词:
N-Cycl[32 2 ]azine 甲酰脲衍生物荧光材料金属离子
Keywords:
N-Cycl[32 2 ]azine formyl urea derivativesfluorescence probesmetal ions
分类号:
O621.2
摘要:
比较了Ca2+、Ni2+、Cu2+、Zn2+、Sn2+、Pb2+、Mn2+、Al3+等8种金属离子对所合成的N-Cycl[3,2,2]azine甲酰脲衍生物荧光性能的影响,旨在探明该化合物衍生物对金属离子的选择识别性.结果发现在所选金属离子中只有Zn2+对其荧光淬灭较为显著,而对其他金属离子几乎无选择性.因此,该化合物衍生物有望能作为识别锌离子的有机荧光探针.
Abstract:
N-Cycl[3,2 ,2 ]azine formyl urea derivatives was synthesized,and the influence of the Cu2 + ,Zn2 + ,Co2 + etc on their fluorescence properties were measured,so as to find these derivatives recognizing properties on some metal ions. The fluorescence can be decreased evidently by the Zinc ions,while the other metal ions showed almost no effect on it. so the compounds are promising to be used as the fluorescent probes for Zinc ions.

参考文献/References:

[1] 江玉亮,邱道骥,吴婧,等. 中氮茚衍生物对金属离子选择识别性的研究[J]. 南京师大学报: 自然科学版, 2008,31 ( 3) : 68-70.
[2] Pu L. Fluorescence of organic molecules in chiral recognition[J]. Chem Rev,2004,104: 1 687-1 716.
[3] Martinez-Manez R. Fluorogenic and chromogenic chemosensors and reagents for anions[J]. Chem Rev,2003, 103: 4 419- 4 476.
[4] Liang Feng,Hu Jiaxin,Zhang Lande,et al. Preparation of pyrrolo[2,1 ,5 -cd]indolizine derivatives by intramolecular condensation of 3-acyl-5-methylindolizines [J]. J Heterocyclic Chem,2001,38: 853-857.
[5] Sippl W. Binding affinity prediction of novel estrogen receptor ligands using receptor-based 3-D QSAR methods [J]. Bioorganic & Medicinal Chemistry,2002,10: 3 741-3 755.
[6] Sayah B. First synthesis of nonracemic ( R) -( + ) -myrmicarin 217[J]. J Org Chem,2000,65: 2 824-2 826.
[7] 张林群,顾玮瑾,陈长信,等. N-Cycl[3,2 ,2 ]azine 甲酰脲衍生物的合成及其荧光性质研究[J]. 化学学报,2010,19 ( 68) : 1 981-1 985.

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备注/Memo

备注/Memo:
基金项目:江苏省普通高等学校自然科学研究计划( 07KJD150097) 、江苏省高校优势学科建设工程资助项目.
通讯联系人:马振毛,实验师,研究方向: 有机化学及功能材料. E-mail: 07015@ njnu. edu. cn
更新日期/Last Update: 2013-03-11