|Table of Contents|

Visible Light-Induced Transition Metal-Catalyzed C-H Functionalization(PDF)

《南京师大学报(自然科学版)》[ISSN:1001-4616/CN:32-1239/N]

Issue:
2021年03期
Page:
45-53
Research Field:
·化学·
Publishing date:

Info

Title:
Visible Light-Induced Transition Metal-Catalyzed C-H Functionalization
Author(s):
Li XuanZhang Jing
The Institute for Advanced Studies,Wuhan University,Wuhan 430072,China
Keywords:
photocatalysistransition metal catalysisvisible lightexcited stateC-H functionalization
PACS:
O621.3
DOI:
10.3969/j.issn.1001-4616.2021.03.008
Abstract:
Visible light-induced transition metal catalysis has become a new type of photocatalytic reaction,which has been rapidly developed in the past few years. Different from the conventional photocatalyst and photocatalyst/transition metal(TM)synergistic catalysis,transition metal complex is the only catalyst in visible light-induced transition metal catalysis. It can not only absorb visible light to convert light energy into chemical energy,but also participate in the cleavage and formation of chemical bonds,playing a dual role in the catalytic cycle. Compared with the traditional transition metal catalysis based on the thermal reaction of the ground state transition metal complex,visible light-induced transition metal catalysis utilizes the unique reactivity of excited transition metal complexes,giving milder reaction conditions,wider substrate scopes,and better selectivity. This review summarizes the latest developments in visible light-induced transition metal catalytic C-H functionalization. The content of this review is classified according to C(sp3)-H and C(sp2)-H functionalization,involving the C-H remote desaturation,alkylation,arylation,amination,borylation and other types of reactions involving Pd,Co,Mn,Ir,Rh,and Ru metal catalysts.

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Last Update: 2021-09-15