[1]杨红晓,张爱民.碳纳米管限域效应及其催化应用研究进展[J].南京师大学报(自然科学版),2011,34(04):64-71.
　Yang Hongxiao,Zhang Aimin.Confinement in Carbon Nanotubes and Its Catalytic Application[J].Journal of Nanjing Normal University(Natural Science Edition),2011,34(04):64-71.
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碳纳米管限域效应及其催化应用研究进展()
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《南京师大学报（自然科学版）》[ISSN:1001-4616/CN:32-1239/N]

卷:
第34卷
期数:
2011年04期
页码:
64-71
栏目:
化学
出版日期:
2011-12-20

文章信息/Info

Title:
Confinement in Carbon Nanotubes and Its Catalytic Application
作者:
杨红晓1; 2; 张爱民2
( 1． 南京大学化学化工学院，江苏南京210093) ( 2． 南京师范大学分析测试中心，江苏南京210046)
Author(s):
Yang Hongxiao1; 2; Zhang Aimin1
1.School of Chemistry & Chemical Engineering,Nanjing University,Nanjing 210093,China
关键词:
碳纳米管; 填充; 限域效应; 催化应用
Keywords:
carbon nanotubes; filling; confinement; catalytic application
分类号:
TB383.1
摘要:
由于碳纳米管(CNTs)独特的结构和性质,使其具备作为催化剂载体的优异条件.通过选择合适的途径将催化剂组装在碳纳米管内部,利用碳纳米管管腔对催化剂性能的调变作用,达到提高催化活性的目的,成为近年来碳纳米管在催化领域研究的热点.结合近年来碳纳米管限域效应研究的成果,介绍了常用的碳纳米管填充方法;概括了碳纳米管对管内填充物氧化还原性、结构相变,以及电学性质的影响等;总结了限域在碳纳米管内的催化反应,并对这一领域今后的研究方向进行了展望.
Abstract:
Carbon nanotubes ( CNTs) are considered to be a promising catalyst support and /or promoter due to their unique properties and special nano-structures． Many studies have shown the improved activity and /or product selectivity in catalytic reaction using CNTs as supports to disperse catalyst inside or outside of it． Especially， the well-defined nanochannels of CNTs draw more attention to investigate the confinement effect of the active phase on the catalytic activity and selectivity． In this minireview，the different strategies for the preparation of such confined nanocatalyst，and the changes of their redox property，phase transition，electronic property as well as the catalytic property that could be expected from the resultant confinement effects are presented，with the aim of highlighting their potential use in catalysis．

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备注/Memo

备注/Memo:
基金项目: 国家自然科学基金( 21073087) ．通讯联系人: 张爱民，教授，博士生导师，研究方向: 催化化学． E-mail: zhangam@ nju． edu． Cn
更新日期/Last Update: 2013-03-21